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Out of the dozen CDI owners I know personally, 5 have the 350, 2 the 250 and 5 have the 220.
All are 2010 onwards cars and the least reliable has unfortunately been the 350 with 2 suffering roadside breakdowns requiring recovery. It was one of the things that convinced me to go with the 250, along with the better 10+ mpg and little real world performance difference between them.
The 350 is a nice smooth engine though.
Just for clarity, I've owned every diesel made by Mercedes since the late 90's. I'm not saying the four pot is a bad engine, it's not, it's just the V6 is so good.Driven both in a convertible a lot and to be honest you can't tell the difference in diesel sound other than at tickover. It is definitely smoother, but really not that faster in real life than the 250.
There weren't anywhere enough positives for me to choose the 350 over the 250 after spending a month with each. If it were performance, then it would have been a petrol every time as they aren't that much less economical on a run than the 350.
4cyl CDI engine is a tough old unit if a bit clattery, earlier 212/204's had problems with injectors.
V6 CDi in the age you're looking at is a peach; 265bhp and mpg will comfortably achieve into the 50s. Suits the E-Class perfectly and feels even more lively in the smaller C-Class.
If you've got the budget, go for the V6, it's almost petrol-like in it's smoothness.
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