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From recollection this figure works out to a further 13p per mile, meaning that in total you should get compensated about 40p per mile for business miles (using a 2.0l petrol car as an example)
It depends how much the mileage allowance is from the company.
If he's getting 26p mile then for the first 10K miles he can claim back the tax on the difference between that and HMRC rate of 45p which is 19p BUT you only get the tax back, so a 40% tax payer gets 7.6p, a 20% tax payer only gets half of that.
Over 10K miles the HMRC rate is 25p so strictly speaking he should be paying tax on 1p per mile.