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Pearlescent is metallic and is exactly how you're describing it, not sure what you're thinking off.
An old thread
http://www.mbclub.co.uk/forums/gene...-paint-v-metallic-paint-whats-difference.html
Pearlescent has teeny weeny glass beads added to the paint, this caused weird light refraction hence you get a multicoloured paint effect (depending on which angle you view it from). Metallic has teeny weeny bits of reflective "stuff" added to the paint, hence light bounces off the relective surface.
...but, ignoring the technicalities, my car is often next to my wife's pearlescent (Diamond White) and the effects are clearly very different.
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