Hi & welcome.
I would check the MOT history to see if the car has been off road / stored for any length of time. R129s don't rust nearly as badly as most other MBs of that era, but check the underside just to be sure. Obviously you can see any MOT advisories online. Check the age and condition of the tyres - things like hoses and suspension bushes can also suffer when a car is standing.
Make sure all electrics work including things like seat and steering column adjustment. These aren't particularly problematic but any issues may be tricky and/or expensive to fix. Check the operation of the hood very carefully - this is complex and has many hydraulic components plus sensors & microswitches. Make sure the roll bar goes up & down on the switch. Problems with this (or the electric windows) will stop the hood from operating. Check the hood rear window for cracking ... this normally starts as a tiny mark each side on the fold line. The hood is under a fair bit of tension when it's up and plastic window failures are reasonably common. If the hood itself is in good condition the windows can be replaced so this isn't a huge deal.
If the car has adaptive damping (ADS) check that it raises & lowers on the height adjustment switch when the engine is running. This is a pretty reliable system compared to the ABC suspension on the later R230, but the hydraulic accumulators ('spheres') have a limited lifespan and can need replacement. If this is the case the suspension will be very hard and the car will 'bounce' on uneven road surfaces. ADS was standard on the V12 SL600 and optional on other R129s (including the rare SL60 AMG). Which engine are you considering? The V8s are pretty bombproof and give a good reserve of power & torque (remember this is basically a 2 tonne car). The straight 6s can suffer from head gasket failures, the later V6s are OK I think. The V12 is big/heavy/complex but again generally OK AFAIK. I would personally steer clear of the 280 as being a bit underpowered, but it's probably fine for gentle cruising. Earlier R129s suffered from the insulation on the wiring looms breaking down, but they should all have had that fixed (new loom) by now.
All cars had a hard top and a wind blocker as standard. The latter quite often got sold off and I've seen the odd car offered for sale without the hard top too! The optional panoramic hard top is quite sought after although I personally prefer the lighter and more angular standard one (which is mostly aluminium).
The main R129 facelifts were in 1996 (5 speed gearbox became standard - visually, 2 vents behind the front wheels rather than 3) and 1999 (different V8 engine - visually, oval door mirrors instead of rectangular). Pre '96 cars often have indicators swapped out for clear ones to make them look younger. Replica AMG wheels are something to watch out for as genuine ones are worth big money. If you have a particular car in mind people would be happy to comment on it, assuming it's advertised online!
FWIW I've owned a 2 previous owner R129 SL500 (1997/P) for 20 years. Currently on 57k miles - it's been reliable and pretty trouble free.
Hope that helps.