If you are just doing the chain , and not the tensioners , it isn't that hard a job .
If you can obtain a Haynes manual , the process is described in there . If you don't have a Haynes manual , many public libraries have them ; you can go in and read through the relevant part before deciding whether you'd feel comfortable doing the job .
The price quoted depends whether the garage is just winding a new chain in and possibly replacing the tensioner as a precaution . I'd be shocked at that £3000 quote unless they plan to strip the engine , and replace the sprockets and guide rails along with the chain and tensioner - unless your engine is noticeably rattly , this should not be needed .
As a very rough guide , to just change the chain , it is along the lines of the following ; I've done a few , but not in recent years .
Remove the spark plugs so you can turn the engine easily by hand ; remove cam cover and rotate to see if existing chain has a splittable link ; this is likely if it has been changed before , otherwise one of the links will have to be cut or broken .
Split chain , taking care not to drop either end in ( a good hint is , before you split the old chain , to get some stiff wire like from a coathanger and hook into the chain a few links along and tie it off so that it can't be dropped in - until you are ready with the new chain joined on ) , then with the new chain joined onto the end of the old one , wind it round by hand until the two ends of the new chain are visible .
Join ends up and check you can still crank the engine round by hand without anything catching before attempting to start it . If you have lost the timing in the process and something is fouling , you will need to refer to the timing marks on the crank and camshafts to get it re-timed before you try to start it . As long as you've only been winding it round by hand , if something fouls , no damage will have been done .
Of course , if there is any noise or rattling at present , you at least need to do the tensioner at the same time ( can be done with care without major upheaval , process also shown in the Haynes manual ) , and also check for wear on the sprockets , which then turns it into a bigger job .