Drive it onto the rollers....test the front brakes by powering up the rollers with a remote control (in neutral) and pushing the brakes several times, engine running of course, looking for smoothness and even-ness of braking side to side....then push it down hard enough to stop the rollers ...noting reading
Drive forward...test the rear brakes in the same way and then test the handbrake......if it's an ALFA....try again and again until your handbrake creeps over the pass mark! The percent is not that important.....exactly the same brakes on different weight cars will give different results. All tests are done in neutral....the rollers age powered by electricity.....not the car.
Four wheel drive cars can't be tested on the rollers so it's done on a short road test using a Tapley meter....a primitive device that is sat in the car and measures braking force by tilting forward under braking.....but cars with softer spring and more front dive get better readings!
Note....I've not been an official tester for over 30 years....so things have probably changed a bit!