You've got damp in the cabin. The rear screen heater is designed to clear frost/ice on the outside not condensation on the inside.
Do you use the a/c all the time?
Do the carpets feel damp, especially around the bottom of the A pillars?
Damp/wet coats in the boot?
It's generally recommended to use the a/c continuously to help dry out the cabin air, especially in the cooler months.
There is a negligible impact on fuel economy and it helps ensure a/c system seals remain well lubricated. Win, win...
CLS500 4.7TT 2012,, SL350 09, 996 cab, all current. Gone :CLS 55 E500 W211, 2x M5s and too many 911s
In winter my car will mist up pretty quickly if I turn the aircon off. It is supposed to be on all the time as even if you have the heater on it makes a huge difference to the "dryness" of the air in the car.....a/c on!