On the STAR system, you can program the overhead control panel (ocp) and tell it what kind of glass you have, factory tinted or non-tinted. I played around with this a bit on my CLK and the wrong setting can cause the mirror to dim in daylight (when it shouldn't dim). Also the OCP, if defective can cause intermittant problems with the dimming functions of the mirror and door mirrors.
Probably best to have someone do a diagnostic via the STaR system, its pretty good at catching these problems.