Hi W210 Fan - Good choice of car!
I looked into ECU reprogramming a while back. Then, it was only available from a German company at around £900 iirc. Delimiting the standard ECU gives around 172mph and with an additional 30bhp released by optimising the ECU they claim this rose by around 10mph. Not that you'd need 180mph in leafy Surrey.
The same deal is on offer from
http://www.speedtuningusa.com but at a more reasonable $325. The first problem is you have to send the ECU away for reprogramming. Then there's all the 'whatifs'. The ECU is very expensive to replace, sending it away to a foreign company may not appeal, and if the fuelling map isn't exactly right you could in a worst case scenario be looking at a new engine. But then, life is short and if the idea works for you, maybe I'd overcome my natural caution and try it too...