If you buy a Brabus enhancement through a UK main dealer then the warranty will remain in tact but will be limited to 60,000 miles (rather than unlimited).
If you buy from a Brabus agent, IIRC and broadly speaking, they will honour any repairs not covered by the warranty but found to be as a direct result of their modification(s). Not sure of the term - I would imagine for the period of the manufacturers guarantee on new cars, and 12 months thereafter. You'd need to check though.
There aren't many MB specialist tuners in the UK -
www.brabus.de,
www.carlsson.de and
www.kleemann.dk both have a UK agent and are traditional tuners (ie not just chip tuning). A member here was dissapointed with the results from Carlsson though IIRC.
As a generic tuner
www.dmsautomotive.com have a very good reputation as a generic chip-tuner. There are hoards of other generic tuners out there though, who often use an off-the-shelf map from the likes of Superchips, RICA and maybe even DMS, and some will tweak some parameters on a rolling road, but fundamentally based upon a core generic map.
I would personally prefer to use an established MB tuner - like Kleemann, Carlsson or Brabus - but all use piggy back tuning boxes, which I'm less keen on than modifying the chip. However all three are market leaders and must have faith in the concept.
Finally there are others worthy of mentioning like
www.bbr-gti.com who traditionally tuned VWs have a reputation for new MINI but will do 'proper' traditional tuning too.