I have just had a similar experience with my W209, except the number plate bolt just wouldn't tighten in the rivnut thread.
When I asked for a rivnut at my local dealer, I was given a plastic fitting (000 998 26 85 - BOXF5 NUT) which looked like the base of a push pin trim clip, except it accepts a 5mm bolt to secure it instead of a push pin.
When I got down to fixing the number plate, I found that a 5x15 bolt protruded just far enough through the rivnut to accept a 5mm nyloc nut. This is probably because I used a Wurth number plate frame whose back is a bit thinner than a number plate. In any case, judicious choice of bolt length would allow for a nut to be fitted.
I guess I was fortunate that my bolts had not seized in the rivnuts, but it did save me having to remove the rivnuts, and the number plate is definitely secure now.