I love the unmistakable sound of a V8, although I think part of it is due to hearing them so rarely, because:
(A) there aren't many V8s about in relative terms,
(B) modern V8s are well silenced, and
(C) the average V8 drivers aren't the type to give it full beans in areas where it will be heard, not like the sort of oiks who share their toonz with us too!!
Despite the greater relative quantity, and because they're not all that common in sporty cars, you don't often hear a V6 wail either. I love them though.
I think V6s sound much better on the outside than on the inside though. A few months ago I asked Mrs D to drive my car so it could pass me, and I got a little too excited when I heard it!! Completely different to inside because you can hear the exhaust note and not just the engine.
Police, Camera, Action was a great way of hearing V6s giving it some as the Omega patrol cars kicking down sound great, and you can be Alasdair Stewart any time you like for very little money with an Omega V6.
Oops, and nearly forgot. My favourite engine/exhaust noise is without doubt a BMW 3.0 straight-6 fitted in a nice E46 3-Series Coupe. A wonderful noise. Surprised I've never had one.