One thing to check is the 'cold start valve'. I had a few VW K-jetronic cars including the Turbo Technics 16V golf development car

I see to remember on the engine block there used to be a rectangular block that bolted to the engine block and had 2 braided fuel hoses coming from the fuel distribution manifold. If memory serves me well it increased th efuel pressure when the engine was cold. A sort of auto choke to increase the pressure and thus make it a richer mixture to aid cold running. If this device has failed it might be making your engine run rich all the time!!!!! I am guessing you have had the CO read and the HC. A simple MoT exhaust gas meter should give you an idea if you are running rich. Well it will at idle at least, I am sure a local garage would give you the figures for a beer or two. You need CO, HC and O readings.
Hope that helps and isnt way off base for your car?