Saga update. I am now convinced the car has had an adblue delete. I checked again with the endoscope before and after pouring in just a couple of litres of adblue and there was a marked difference in how it looked. I think the tank was nothing but droplets before - bone dry. The reason I didn't realise the camera was scraping the bottom of the tank was because it was just droplets, so I thought it was a tank wall. After pouring in a bit, I could clearly see the liquid level.
I only did a little bit because the anti crystal stuff makes it really foamy and even with only a little bit added it bubbled out of the filler neck and spilled. So I'll just do a bit at a time and test drive it at some point. Anyways I think that's this mystery solved lol. We'll see what happens after I drive it and add more in.
For those who find this in the future and want to drain and refill your tank on a non-adblue-gutted C-Class here are some tips:
You need a syphon, I got a cheap bulb pump kind off of eBay:
View attachment 152142
The hose will probably be too stiff so go back onto ebay and get yourself a 6mm-8mm flexible PVC hose and some plastic pipe reducers to connect the thinner hose to your syphon.
Thread that through your filler neck. There are no obstructions, valves or anything in the filler neck. There is a 90 degree bend and the filler neck walls are quite rough and have some notches and such the pipe can catch on. If it gets stuck just keep twiddling it and trying to bend it until it goes past the 90 degree bend. After that it's a straight shot into the tank, you'll hit the pump thing and then the hose will slide past that to the bottom of the tank where it'll stop. Syphon as much out as you can.
I put the anti-crystal stuff in the adblue before adding it into the tank to mix it - don't know if that's a good idea but this stuff really does froth a lot, it's like detergent. Keep cloths/paper towels nearby - don't get this nasty stuff on your paintwork. My adblue container was leaky as hell with the supplied nozzle thing.
Thank you all for joining me on my adblue saga of discovery