^^^ Got jumped. The question about the secondary cats, do the filter the gasses further even though they are cooler than the primary or are they there to give back pressure. /
Cheers
Ideally, there would be just one catalyst that warms up quickly and has enough internal surface area to process the exhaust gases produced over the full operating range of the engine. This used to be the normal arrangement, but as the emissions regulations tightened up, the single catalyst didn't light up quickly enough to manage the initial cold start emissions well enough to pass the regulated test.
Solution; put another catalyst nearer to the engine that gets going more quickly hence giving time for the main catalyst to get up to working temperature. Typically though, this catalyst can't cope with the emissions over the full operating range if the engine. The additional (main) catalyst provides more (usually a lot more) surface area that can then process the emissions from when the engine is working hard.
There is a question as to whether the exhaust emissions aftertreatment systems are optimally sized to just cope with emissions made by the engine when working at the speeds and loads defined by the standard test cycles or whether they can manage the emissions over the whole operating range of the engine.
For sure the catalysts, silencers, DPF, turbochargers, EGR valves etc. introduce restrictions to the exhaust gas flow. When looking for performance, ideally the intake and exhaust systems would be optimised. But do you optimise for best power, best torque, best driveability, best sound etc.? In the end there are compromises to make. The catalysts and other after treatment devices are installed by mandate to minimise exhaust pollutants (CO, HC, NOx, PM) leaving just CO2 and water. Taking some of the devices out of the system does compromise the 'cleaning' performance and undermines the whole point of having them in the first place.