Actually V-Power isn't very stable. Neither was Optimax. RON rating degrades over time so fresh V-Power is usually higher than 99 but it could be worse depending on when it was last refreshed.
That's why they took the RON rating off the pumps because Optimax wasn't guaranteed to be 98 which Shell originally advertised.
I don't think it's anything specifically to do with being V-Power or Optimax. All gasoline degrades, and in fact diesel does too.
I suspect the issue is just that 'premium' fuels can spend longer in the storage tanks because they don't sell at the same rate as standard grades.