Not sure about the new system but at an S-Class meet last year, someone's lady friend managed to lock themselves out because the key was in the lady's handbag and she pressed the close boot lid only button (car was in a locked state)... 04 plate S55, the boot and doors would not open, even with the key in the boot.
I have tested this with my car and the boot lid will continue to close.
I have tested this with my car and the boot lid will continue to close.
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