There is more to running on unleaded than just the octane rating. I'll repeat here what I wrote in an earlier post.
Lead (as tetraethyl lead) was added to petrol to indeed boost the octane rating. This allowed higher compression ratios leading to increased power and efficiency. This lead then coated the combustion train, as can be seen in the white deposit on the inside of the tailpipe of a 'leaded' car. This was found to have a cushioning effect on the valves as they repeatedly impacted against their seats. In black and white days, this wasn't too important because engines were low-revving and had little valve lift, so the impacts were not too severe. As power outputs increased, due in part to higher revs and greater valve lift, these impacts became harder and more frequent. Then Shell tried introducing unleaded fuel without telling anyone. Vauxhalls in particular were badly affected by this. The cast iron valve seats quickly became 'pocketed' and the hydraulic tappets ran out of adjustment. Because this cushioning layer of lead was no longer present, the constant impacts between valve (particularly the exhaust valve) and seat wore the seat away. Shell eventually owned up.
When time was called on leaded fuel, many engineering shops had a nice sideline going in replacing cast iron valve seats with more modern ones made from (I think) austenitic steel (or is it iron?).
So, as well as the ignition timing, check the valve seat material. It could save you an expensive rebuild.