I would think it's more likely to be a W210, but you never know! If it is, then rust is your big enemy - there are a few better examples around, but the rot gets them all eventually. Apart from the places Killerhertz has mentioned, tops of doors, front spring perches and front crossmember also should be checked. It'll be the IL6 engine, so fairly bulletproof overall, but inlet port shutoff motors can give problems, as can EGR valves. Check to see if the gearbox fluid has been changed - it really needs doing every 40,000 miles or so.
If it's a W211, the front arches can't rust, as they're aluminium. They don't all have SBC suspension, so best to get one without if you can. The Valeo radiator problem should all be fixed by now, so I doubt you'd find one, but you just never know. If it is an affected model, avoid like the plague, as it will cost LOTS to fix it!