Which engine oil do I use for a service for a 1992 Mercedes W124 300e Petrol Automatic
The original MB spec would have been 229.1 which has long been superseded first by 229.3 then 229.5 and more recently by 229.6 and 229.7.
Any of those specs will be backwards compatible but there is no chance you will find any oil to 229.1 and no good reason to use it if you did as later specs are better. You can still find 229.3 and 229.5 as MB still provide a list of approved oils.
Mercedes-Benz Operating Fluids
Mercedes-Benz Operating Fluids
If not insisting on an MB approved oil, then the bottom line should be that any oil you use meets Acea A3/B4. If you do that you can't go far wrong.