It doesn't really matter what the battery voltage is as such, as we have an idea of how much energy we put in when charging (mains supply volts, current and time of charge). It's this charging energy that matters to us as users I think - it's the only thing we can actually measure ourselves, after all.
The things that might be nice to know would be what the upper and lower buffer amounts are, so we could have a better idea of the actual usable capacity of a nominally perfect battery pack. We don't even know if the quoted 6.3kWh is net or gross. I guess gross myself - the net usable (after taking off the buffers) I can see MB wanting to keep quiet about for a number of reasons. As time passes and they gather more data about battery usage and life, they may well want to increase those buffers to reduce capacity loss. Of course, if they do that, it would mean we'd immediately lose some usable capacity, but longer term, it would mean the battery lasts better overall.
The other things we don't know are charging efficiency and overheads, so even if we put 6kWh in to the car, we don't really know how much of that actually ends up as useful charge in the battery itself - basic charging efficiency is probably about 95% but there are other overheads as well like the battery thermal management that we have absolutely no idea about.