To be fair it isn't that easy to get them spot on. Having inflated up to the heavy car setting I have now reduced the pressure to the standard settings. Before and after I have noticed how sensitive tyres are to heat even the difference between the shady side and the sunny side of the car can give a difference of 10kpa. The recommended tyre pressures are for warm tyres too.
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The tyres on the left that have higher pressures are normally on the shady side. I guess that could make a difference.
Are you sure about the recommended pressures being for warm tyres? The manual says "tire pressure cold tires"...